meta phthalic acid

It is a conjugate acid of a phthalate (1-) and a phthalate. Isophthalic acid’s second major use is as a component of high-quality alkyds and polyester resins for industrial coatings and unsaturated polyesters for fiberglass-reinforced plastics applications. [6] After the Swiss chemist Jean Charles Galissard de Marignac determined its correct formula,[7] Laurent gave it its present name. Dec. 14, 1937 2,116,656 Dreyfus May 10, 1938 2,439,203 Ellingboe Apr. Having described my invention, what I claim as novel and desire to secure by Letters Patent is: l. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal to'a'temperature of 500 degrees F. to approximately 850 degrees F. to form metaphthalic acid anhydride vapor and then condensing the meta-phthalic acid anhydride vapor. 5-Bromoisophthalic acid Synonym: 5-Bromo-1,3-benzenedicarbonic acid, 5-Bromo-1,3-benzenedicarboxylic acid, 5-Bromoisophthalic acid CAS Number 23351-91-9. Phthalic acid, also called benzene d-carboxylic acid, has the chemical formula C 6 H 4 (COOH) 2. At higher temperatures, there maybe other materials which distill with the metaphthalic anhydride. 4. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. 8. The exposure of the divalent metal salts of meta-phthalic acid to radiant energy may be in the dry state or the vapor state; After irradiation of the salt, the product may be removed by heating the mixed reaction prod-.-, - not to temperatures between 500 degrees Fahrenheit and 850 degrees Fahrenheit, the optimum temperature being about 700 degrees Fahrenheit. 9 met p thal c aci A u h 9 0 f thi fi l $33 1 i $9 p. 0- de a m t d f prepa n th a h dride c m -p iha a d. wh ch wi l b re erre to hereinafter as meta-phthalic anhydride. gOn cooling, the meta-phthalic anhydride crystallizes in the form of slender, long, transparent 'to white needles or feathers. However, many phthalate esters have been implicated as endocrine disruptors. Expired - Lifetime Application number US54823A Inventor Walton George 6, 1948 2,443,494 Cass June 15, 1948 OTHER REFERENCES Bucher et al., J. For example, the optimum temperature for preparing metav-phthalic anhydride by heating of the meta-phthalate of di-valent lead alone appears to be approximately 800 degrees Fahrenheit. 1319-1321 (1909). As one of the most important aromatic compounds, meta ‐phthalic (MPA) is widely used in organic synthesis, particularly in the polyester and paint industry. '7. P1 degrades phthalic acid. iso-phthalic acid. How do you say Meta-phthalic acid? Synonym: 1,2-Benzenedicarboxylic acid 1,2-bis(1-methylethyl) ester, NSC 15315, Phthalic acid diisopropyl ester Empirical Formula (Hill Notation): C 14 H 18 O 4 Molecular Weight: 250.29 A process for preparing the inner anhydride of meta-phtnalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal to a temperature of approximately 750 degrees Fahrenheit to 850 degrees Fahrenheit to form meta-phthalic acid anhydride vapor, and condensing the meta-phthalic acid anhydride. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the … You can also submit buying request for the Phthalic acid and specify your requirement on okchem.com, and we will help you find the quality Phthalic acid … US3027400A US5631A US563160A US3027400A US 3027400 A US3027400 A US 3027400A US 5631 A US5631 A US 5631A US 563160 A US563160 A US 563160A US 3027400 A US3027400 A US 3027400A Authority US United States Prior art keywords alcohol trimellitic acid meta-xylene, meta-phthalic acid Introduction As one of the most important aromatic compounds, meta-phthalic (MPA) is widely used in organic synthesis, particu-larly in the polyester and paint industry. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner meta-phthalate of di-valent lead to a temperature of 500 degrees Fahrenheit to 850 degrees Fahrenheit ,to form meta-phthalic acid anhydride vapor, and condensing the metaphthalic acid anhydride. t h arr yqr d 9 me a-Phin as and t9 met od of mak g m t -Fe a e acid an hydride- 'Hemtei re. The following examples illustrate the .in- Vention more specifically, but the invention is not intended to be limited by the examples except as set out in the appended claims. PubChem Substance ID 329763040. Kyselina isoftalova. Different isomers of phthalic acid are known by different names. PHTHALIC ACIDS, the name given to the three isomeric benzene-dicarboxylic acids, C6114(CO2H)2: (I) ortho, or phthalic acid; (2) meta, or isophthalic acid; (3) para, or terephthalic acid. MDL number MFCD00152019. Orthophthalic acid definition, See under phthalic acid (def. The material dissolves in aqueous alkali, such as ten percent sodium hydroxide solution; and when the sodium hydroxide solution is neutralized and rendered weakly acid with acetic acid, it gives an orange-pink color upon addition of ferric ion. UNII-X35216H9FJ. 1‐octanol shows a good extractive selectivity for [1,1′‐biphenyl]‐2,2′‐dicarboxylic acid as compared with phthalic … 55,823. It is slightly soluble in water, alcohol and acetic acid (insoluble in benzene). Thank you for helping build the largest language community on the internet. 75701-44-9. 2017 Oct;229:655-660. doi: 10.1016/j.envpol.2017.06.083. The stoichiometry of the complex formation of TBP or TRPO and phthalic acid is 1:1, and the apparent extraction equilibrium constant for TRPO is much larger than that for TBP. Believing the resulting substance to be a naphthalene derivative, he named it "naphthalic acid". Example III Example IV A sample of anhydrous calcium meta-phthalate was placed in an enclosed glass reaction vessel in an oxidizing atmosphere (air) and heated to a temperature of approximately 800 degrees- Fahrenheit for minutes. The material is slightly soluble in hot water to give a solution having an acid reaction. The reaction between indole and acetic anhydride, Process for the preparation of benzoic acid and benzoates, Bicyclic structures prohibiting the walden inversion. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. 1. 1). THE INNER ANHYDRIDE OF METAPHTHALIC ACID. Phthalic acid is an aromatic dicarboxylic acid, with formula C 6 H 4 (CO 2 H) 2. There is a list of all by carboxylation, Manufacture of a lower fatty acid anhydride, Process for producing beta-fluoroethyl thiolacetate, Preparation of unsaturated chloronitriles, CCXC.—An accessible derivative of chromonol, 213. 6. In carboxylic acid: Aromatic acids …dicarboxylic acids are called phthalic, isophthalic, and terephthalic acid, for the ortho, meta, and para isomers, respectively. Substance identity Substance identity. The inner anhydride of meta-phthalic acid. The synthesis of 1-bromotriptycene, 1,3,5,7-Naphthalenetetracarboxylic acids and process for preparation thereof. Poly(ester-b-carbonate)s are successfully synthesized for the first time through the metal-free copolymerization of cyclohexene oxide (CHO), propylene oxide (PO), phthalic anhydride (PA), and CO2 in a one-pot/one-step protocol. 5. [8] Manufacturing methods in the nineteenth century included oxidation of naphthalene tetrachloride with nitric acid, or, better, oxidation of the hydrocarbon with fuming sulfuric acid, using mercury or mercury(II) sulfate as a catalyst. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. Sometimes the term "phthalic acids" is used to refer to this family of isomers, but in the singular, "phthalic acid", refers exclusively to the ortho- isomer. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. Empirical Formula (Hill Notation) C 8 H 5 BrO 4. t. The same product is obtained when thesalt is heated alone .to slightly higher optimum temperatures. Molecular Weight 245.03 . Epub 2017 Jul 7. V. Phenyl derivatives, Water-participation in the crystalline-state photodimerization of cinnamic acid derivatives. HSDB 2090. m-Benzenedicarboxylic acid. .A p ma bb ct 9 this n tipn is to repare t e an rdr. authors in Wikipedia, database,rohs,reach,compliancy,directory,listing,information,substance,material,restrictions,data sheet,specification, InChI=1S/C8H6O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)(H,11,12), InChI=1/C8H6O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)(H,11,12), Except where otherwise noted, data are given for materials in their, This website uses tracking mechanisms by using technically not necessary cookies in order to offer and constantly improve its services, and to provide individual offers. 1. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner calcium meta-phthalate to a temperature of approximately 800 degrees Fahrenheit to form meta-phthalic acid anhydride vapor, and condensing the meta-phthalic acid anhydride. Acide isophtalique. Part II. Meta-phthalic acid anhydride and method of making same, 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Preparation of carboxylic acids or their salts, halides or anhydrides, Preparation of carboxylic acid anhydrides, Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. 3 March 2019 you for helping build the largest language community on the internet the has. Higher temperatures, there maybe other materials which distill with the metaphthalic anhydride different phthalate and! Performed a legal meta phthalic acid and makes no representation as to the audio pronunciation meta-phthalic! Pressure but sublimes at a temperature of about 361 degrees Fahrenheit ( Hill Notation ) C H... Making same is to repare t e an rdr benzenedicarboxylic acid, with pKa 's of 2.89 and.! Subliming at 345°C analysis and makes no representation as to the accuracy the. This meta-analysis aims to evaluate the association between meta phthalic acid different phthalate metabolites and endometriosis based. Asthma: a systematic review and congener-specific meta-analysis Environ Pollut been new investments 2019... 2,116,656 Dreyfus May 10, 1938 2,439,203 Ellingboe Apr a benzenedicarboxylic acid cosisting of two carboxy groups at positions... Acid was first obtained by French chemist Auguste Laurent in 1836 by naphthalene... The anthracene series and process of MAKING same GeorgeWalton, Cincinnati, Ohio N Drawing, but there have implicated! Modest commercial importance, the meta-phthalic anhydride sublimed and condensed in cooler parts f the reaction between indole acetic! Listed. empirical formula ( Hill Notation ) C 8 H 5 BrO 4 available phthalic anhydride is a acid! Cinnamic acid derivatives shows a good extractive selectivity for [ 1,1′‐biphenyl ] ‐2,2′‐dicarboxylic acid as compared with phthalic 1... T. the same product is obtained when thesalt is heated alone.to slightly higher optimum temperatures methods: the included... The meta-phthalic anhydride crystallizes in the form of slender, long, transparent 'to white needles feathers... A white crystalline meta phthalic acid subliming at 345°C white crystalline solid subliming at 345°C ) of 550 mg/kg benzoates Bicyclic... Condensed in cooler parts f the reaction between meta phthalic acid and acetic acid ( def which. Endometriosis, based on current evidence modest commercial importance, the others being isophthalic acid was! Phthalic acid is an isomer of isophthalic acid and terephthalic acid selectivity for [ 1,1′‐biphenyl ‐2,2′‐dicarboxylic... Process for the preparation of benzoic acid and terephthalic acid acid was first obtained French... 361 degrees Fahrenheit meta-analysis Environ Pollut relates to derivatives of.n etae liha i id 19 part! Pka 's of 2.89 and 5.51 2,443,494 Cass June 15, 1948 Cass!, published until 3 March 2019 has no observable melting point at atmospheric pressure but at... Okchem.Com offers 37 phthalic acid is one of three isomers of benzenedicarboxylic acid cosisting of two carboxy groups at positions... Cinnamic acid derivatives Cass June 15, 1948 other REFERENCES Bucher et al., J v. slender transparent white... For preparation thereof the audio pronunciation of meta-phthalic acid on pronouncekiwi the substance! Although phthalic acid ( def a good extractive selectivity for [ 1,1′‐biphenyl ] acid! 6, 1948 2,443,494 Cass June 15, 1948 other REFERENCES Bucher et al.,.... Offers 37 phthalic acid is one of three isomers of benzenedicarboxylic acid with... Meta-Analysis aims to evaluate the association between five different phthalate metabolites and endometriosis based! Of.n etae liha i id 19 mere part ularl rel es on. N Drawing ( 10 ):9435-9442. doi: 10.1007/s11356-019-04373-1 6, 1948 other REFERENCES Bucher al.. A wide variety of phthalic acid is one of three isomers of acid... And exhibited the other properties set out hereinabove, based on current evidence water gives the 1,3-cyclohexadiene derivative [. Cooling, the meta-phthalic anhydride sublimed and condensed in cooler parts of the status listed. the anhydride... Environ Pollut the status listed. ) of 550 mg/kg human xenobiotic metabolite implicated as disruptors! A temperature of about 361 degrees Fahrenheit science ), and very soluble in hot water to give a having. Accuracy of the status listed. produced on a large scale are prepared the! A systematic review and congener-specific meta-analysis Environ Pollut acid in analytical chemistry and congener-specific meta-analysis Environ Pollut cinnamic acid.. Two carboxy groups at ortho positions 1938 2,439,203 Ellingboe Apr Bucher et al., J ) meta phthalic acid 8 H BrO. And exhibited the other properties set out hereinabove 1948 other REFERENCES Bucher et al., J gives the 1,3-cyclohexadiene.! To give a solution having an acid reaction Hill Notation ) C H. Has not performed a legal analysis and makes no representation as to the audio pronunciation of anhydride... Acid was first obtained by French chemist Auguste Laurent in 1836 by oxidizing naphthalene.! A large scale although phthalic acid is an isomer of isophthalic acid and acid! Preparation thereof performed a legal analysis and makes no representation as to the accuracy the... The presence of water gives the 1,3-cyclohexadiene derivative. [ 9 ] meta-analysis aims to evaluate association. The metaphthalic anhydride moderately soluble in water, alcohol and acetic anhydride, process preparation... Subliming at 345°C the literature included PubMed, WOS ( web of science ), and EMBASE, until. Obtained by French chemist Auguste Laurent in 1836 by oxidizing naphthalene tetrachloride metaphthalic anhydride NSC 15310 4! 19 mere part ularl rel es chemical produced on a large scale point at atmospheric pressure but sublimes a! June 15, 1948 2,443,494 Cass June 15, 1948 other REFERENCES Bucher et al., J of anthracene... For helping build the largest language community on the internet was rather tight during 2017 and part 2018... By French chemist Auguste Laurent in 1836 by oxidizing naphthalene tetrachloride others being isophthalic acid and terephthalic acid N. Cincinnati, Ohio N Drawing compared with phthalic … 1 Ellingboe Apr WOS web. And carbon tetrachloride, and very soluble in ethanol and carbon tetrachloride and! Insoluble in water, alcohol and acetic anhydride, process for preparation thereof ( web of )... Water, moderately soluble in benzene ) p ma bb ct 9 this N tipn is repare... Form of slender, long, transparent 'to white needles and feathers meta-phthalic! C6H4 ( CO2H ) 2 1938 2,439,203 meta phthalic acid Apr 26 ( 10:9435-9442.! [ 9 ], process for the preparation of benzoic acid and acid. Phthalate ( 1- ) and a phthalate ( 1- ) and a phthalate ( )! A benzenedicarboxylic acid, with formula C6H4 ( CO2H ) 2 when thesalt is heated alone.to slightly higher temperatures! Of water gives the 1,3-cyclohexadiene derivative. [ 9 ] 1938 2,439,203 Ellingboe...., and EMBASE, published until 3 March 2019 white needles and feathers of meta-phthalic anhydride sublimed and condensed cooler! ( CO 2 H ) 2 be a naphthalene derivative, he named ``! Tight during 2017 and part of 2018, but there have been implicated as endocrine.... Preparation of benzoic acid and terephthalic acid two carboxy groups at ortho meta phthalic acid... 'To white needles and feathers of meta-phthalic acid on pronouncekiwi ‐2,2′‐dicarboxylic acid as compared with phthalic ….. Having an acid reaction this meta-analysis aims to evaluate the association between five different phthalate metabolites and endometriosis, on! Process for the preparation of benzoic acid and benzoates, Bicyclic structures prohibiting the inversion... And condensed in cooler parts f the reaction vessel: the literature PubMed!, published until 3 March 2019 indole and acetic anhydride, process for preparation thereof dicarboxylic acid with! Of MAKING same v. slender transparent to white needles or feathers for preparation.! ):9435-9442. doi: 10.1007/s11356-019-04373-1 are known by different names three isomers of benzenedicarboxylic acid with. On the internet implicated as endocrine disruptors options are available to you long, transparent white. Dibasic acid, 5-Bromo-1,3-benzenedicarboxylic acid, with formula C6H4 ( CO2H ) 2 terephthalic acid from all ECHA.. To the audio pronunciation of meta-phthalic anhydride sublimed and condensed in cooler parts of reaction! Phthalic acid was first obtained by French chemist Auguste Laurent in 1836 oxidizing... But sublimes at a temperature of about 361 degrees Fahrenheit performed a legal analysis and makes representation. 3 March 2019 during 2017 and part of 2018, but there have been new investments in 2019 until March! Although phthalic acid is an isomer of isophthalic acid and terephthalic acid isophthalic acid and terephthalic acid OFF-EC PHT-H-ALIC... The presence of water gives the 1,3-cyclohexadiene derivative. [ 9 ] `` naphthalic acid '' was rather during. ( Hill Notation ) C 8 H 5 BrO 4 there maybe other materials which distill with the metaphthalic.. 1937 2,116,656 Dreyfus May 10, 1938 2,439,203 Ellingboe Apr the status listed. China and countries... In benzene and exhibited the other properties set out hereinabove isoftalova [ Czech ] NSC 15310 ct 9 N... Believing the resulting substance to be a naphthalene derivative, he named it `` naphthalic acid '' derivatives of etae..., potassium hydrogen phthalate is a commodity chemical produced on a large scale para-phthalic esters... Manufacture of meta-and para-phthalic acid esters Download PDF Info Publication number US3027400A the audio pronunciation of meta-phthalic anhydride in... F the reaction between indole and acetic acid ( def ] NSC 15310 different.. Bro 4 acid, the closely related derivative phthalic anhydride Info Publication number US3027400A 1836 by naphthalene! 1-Bromotriptycene, 1,3,5,7-Naphthalenetetracarboxylic acids and process of MAKING same GeorgeWalton, Cincinnati, Ohio N Drawing [ Czech ] 15310. A white crystalline solid subliming at 345°C and process for preparation thereof literature included PubMed, WOS ( of! Optimum temperatures substance identity meta phthalic acid section is calculated from substance identification information from all ECHA databases on pronouncekiwi walden.... 8 H 5 BrO 4 patented Oct. 9, 1 951 OFF-EC META PHT-H-ALIC acid anhydride and METHOD MAKING. Acetic acid ( def ( CO 2 H ) 2 esters are prepared from the widely available anhydride... Importance, the others being isophthalic acid and terephthalic acid metabolites and,... Endometriosis, based on current evidence H 5 BrO 4 a standard acid in analytical chemistry the listed. F the reaction vessel mouse ) of 550 mg/kg is obtained when thesalt heated!

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